1st off PK'ing = Player killing. You go to a certain world (like 17 or 32) which are worlds that you can kill other players on. To PK, you bring food, armour and of course weapon/s. Its just like killing any NPC's. Click attack to attack them, and eat on low health. But beware, if you die, you don't have a gravestone so you can't get you're items back. Also there are a lot of clans out now-a-days, So don't go deep PK'ing.
Also, Because you're new to PK'ing, I suggest you 1st PK in Monk robes and a Rune scim (or anything like that) so you're not risking anything and make sure you go to a world marked with +1.
It's pretty simple. The most advanced part is learning what levels to get. I'll let someone else fill you in with more details, but here are the basics.
The 'F' keys are direct commands to different tabs for your character.
F1=Inventory
F3=Prayer
F4=Mage book
F5=Special attack tab.
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